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Thermodynamics - II
SUBJECT : Engineering Chemistry
AUTHOR : K K Padmanabha
PUBLISHED ON : 29/03/18
NUMBER OF PAGES : ( 16 Pages)
PRICE : Rs 10.4

For a reaction to be spontaneous, total entropy change should be positive. If it is zero, the system is at equilibrium. But in some cases, the process is spontaneous in spite of decrease in entropy. Ex: At 0oC water spontaneously solidifies, but entropy decreases. Hence we have to consider entropy change in terms of other state functions which can be determined more conveniently. Two such functions are work function (A) and free energy function (G).

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